It takes the average reader 8 hours and 26 minutes to read Housane Radical Cation Chemistry and Its Application to Natural Product Synthesis Using Indirect Electrolysis by Young Sam Park
Assuming a reading speed of 250 words per minute. Learn more
Oxidation of housanes leads to cleavage of a strained sigma bond and is followed by a Wagner-Meerwein rearrangement to transform the framework to a cyclopentene, once a back electron transfer occurs. The rearrangement of housane cation radicals is initiated by both a chemical electron transfer pathway and an electrochemically mediated pathway. Indirect electrolysis using tris(4-bromophenyl)amine as an electrocatalyst is preferred as the oxidation method. Application of this transformation en route to the synthesis of the (n.3.0) framework of natural products requires the assembly of functionalized housanes that will lead to regioselective rearrangement. The mechanistic investigation of electrochemically mediated rearrangement reactions of housane cation radicals, the characterization of the intermediates by quantum calculations, and electron transfer dynamics are described. Using the electrocatalytic transformation as a key step, daucene, a well-known member of the carotane class of sesquiterpenes, was synthesized in a concise manner from a functionalized spiro(4.5)decane system.
Housane Radical Cation Chemistry and Its Application to Natural Product Synthesis Using Indirect Electrolysis by Young Sam Park is 502 pages long, and a total of 126,504 words.
This makes it 169% the length of the average book. It also has 155% more words than the average book.
The average oral reading speed is 183 words per minute. This means it takes 11 hours and 31 minutes to read Housane Radical Cation Chemistry and Its Application to Natural Product Synthesis Using Indirect Electrolysis aloud.
Housane Radical Cation Chemistry and Its Application to Natural Product Synthesis Using Indirect Electrolysis is suitable for students ages 12 and up.
Note that there may be other factors that effect this rating besides length that are not factored in on this page. This may include things like complex language or sensitive topics not suitable for students of certain ages.
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